Nano macromolecule microball of carboxy function type cross-linked nucleocapsid structure and preparation process thereof |
Title: |
Nano macromolecule microball of carboxy function type cross-linked nucleocapsid structure and preparation process thereof |
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Application Number: |
200410008466 |
Application Date: |
2004/03/12 |
Announcement Date: |
2005/01/05 |
Pub. Date: |
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Publication Number: |
1560095 |
Announcement Number: |
1246352 |
Grant Date: |
2006-3-22 |
Granted Pub. Date: |
2006-3-22 |
ApplicationType: |
Invention |
State/Country: |
11[China|beijing] |
IPC: |
C08F 212/08,C08F 220/00, C08F 2/16 |
Applicant(s): |
Tsinghua Univ. |
Inventor(s): |
Yu Jian, Zeng Cheng, Guo Zhaoxia |
Key Words: |
Nano macromolecule microball, carboxy function type, cross-linked nucleocapsid structure,preparation |
Abstract: |
The invention is a carboxyl functional cross-linked core-shell nano high molecular microsphere and its preparing method, using multiple alkene monomers and alkene monomers with carboxyl functional groups as raw materials, on the condition of emulsifier, initiator and buffering agent, and preparing it by emulsion or suspension polymerization using water as medium; the product has a cross-linked structure inside both the core and shell, the core and shell are linked through chemical bonds, the carboxyl functional groups are grafted on the microsphere surface, and the particle size is less than 100 nm. By changing the composition of the core and shell, it obtains a nano high molecular microsphere with multiple different physico-chemical properties, and has very high freedom in selecting structure design. It solves the problem that the precious core-shell high molecular microshperes have no nano size and that the precious cores and shells are mostly linear polymers, and simultaneously by introducing ionizable and reactable carboxyl functional groups on the surface, and makes this microsphere have a completely wide application prospect in nano technical filed. |
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