Jilin Petrochemical Company is the biggest Acrylonitrile production base
in China. Its current production capacity is 212,000 tons/year.
New equipment with the production capacity of 106,000
tons/year was built and put into production in
2007. However, during the production process of Acrylonitrile, a great deal of waste water will be generated. Part
of the high concentration organic waste water contains hypertoxic
cyanide compounds. If it flows into the biological treatment
equipment for waste water, a large sum of bacteria will die. At present, factories
mainly adopt the burning method to deal with the cyanide-bearing
waste water. Every year, 20,000 – 30,000 tons of fuel oil is consumed
to burn 200,000 tons of waste water. The cost amounts to millions
of Renminbi.
For several years, Jilin Petrochemical Corporation has been
looking for an alternative treatment method in order to lower
the cost of waste water treatment. The effect of an irradiation
technology provided by an America company was remarkable in
dealing with this waste water. However, because of the restraints
in technology export of US, it can not be imported to China. Consequently,
Jilin Petrochemical Company decided to develop irradiation
technology independently to dispose waste water.
The first step was to conduct feasibility demonstration.
However, Jilin Petrochemical Company could not find a way out to carry out this demonstration.,
because 1)there was industrial irradiation equipments in the market,
but the price was high; 2) a large quantity of supporting
facilities had to be invested; 3)there was a lack
of qualified personnel; 4)the ultimate object of buying irradiation equipemnt and supporting facilities
was to use them in production. However, this expensive equipments
bought during the experiment stage would be discarded after
the factory put into production,which is uneconomic.
In this case, Coway provided Jilin Petrochemical
Company with a satisfactory solution. The solution was to conduct
prophase demonstration by using the irradiation experiment
equipment of the Institute of Nuclear and New Energy Technology,
Tsinghua University. This equipment employed (60) Co as the irradiation
source, which was appropriate for doing irradiation experiment
to small samples. The experts of the Institute of Nuclear and
New Energy Technology were rich in experience and good at the
operation of the equipment. Furthermore, they were able to provide
appropriate experiment plan according to the features of water
sample. Jilin Petrochemical Company only paid the research experiment fee,without investing too much on capital and human resources on the feasibility demonstration.
The result of the irradiation experiment showed that using
irradiation method could get rid of the hypertoxic cyanide compounds
effectively in waste water. But this method could not remove
the inorganic pollutants in the waste water. Only by integrating the other measures could
the problem of pollution be solved. Moreover, completely using
irradiation would result in higher energy consumption and
lower economic efficiency. Therefore, an integrated technology
solution had to be developed so as to remove all of the pollutants,
cut down irradiation time and improve economic efficiency.Based on the recognition of the prophase experiment service, Jilin Petrochemical
Company entrusted Coway and the Institute of Nuclear and
New Energy Technology, Tsinghua University to provide the development
and research service of the irradiation-biological integration treatment technology for Acrylonitrile waste water..
Through laboratory test, Coway and the Institute of Nuclear
and New Energy Technology developed a treatment solution integrating
irradiation, membrane technology and biological method. this
solution was able to lower the waste water treatment cost greatly.
It also offered a good solution to the problem of Acrylonitrile
waste water treatment that has troubled Jilin Petrochemical
Company for a long time. At present, this project has already been set up
in PetroChina and the further model experiments are underway.